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                    1. www国产精品视频_亚洲精品天堂_久久久久亚洲精品_国产又大又硬又粗_来一水AV@lysav

                      Technical articles技術(shù)文章
                      首頁 > 技術(shù)文章 >利用H-Cube 連續(xù)流動(dòng)氫化儀及納米級(jí)鉑催化劑選擇性還原肉桂醛

                      利用H-Cube 連續(xù)流動(dòng)氫化儀及納米級(jí)鉑催化劑選擇性還原肉桂醛

                       更新時(shí)間:2012-08-24 點(diǎn)擊量:1681

                      INTRODUCTION
                      Selective catalytic hydrogenation of a-b-unsaturated aldehydes is an important step in the industrial preparation of fine chemicals and attracts much interest for fundamental research in catalysis1. Cinnamyl alcohol plays an important role in the perfume and flavouring industries. The process can, however, lead to three different products: saturated aldehyde, saturated alcohol
                      and the desired unsaturated alcohol (see Scheme 1.). The hydrogenation of the C=C bond in a-b-unsaturated aldehydes is both kinetically and thermodynamically more favorable than that of the C=O group2. The most significant factors determining the selectivity are: the type and the structure of the active metal, the type of the substrate, and the conditions of the reaction,
                      namely, the hydrogen pressure and the reaction temperature. The influence of the latter factors can be easily investigated by using the H-Cube®, which is a standalone hydrogenation reactor combining continuous-flow microchemistry with on-demand hydrogen generation and a disposable catalyst cartridge (CatCart®) system3.


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